The 2013–14 season was Villarreal Club de Fútbol's 91st season in existence and the club's first season back in the top flight of Spanish football since 2012. In addition to the domestic league, Villarreal participated in this season's edition of the Copa del Rey. The season covered the period from 1 July 2013 to 30 June 2014.
Source: La Liga, ESPN Rules for classification: [4] 1st points; 2nd head-to-head points; Notes:
^Sevilla automatically qualified for the 2014–15 UEFA Europa League group stage as the defending champions; the berth through their league position was vacated.
^ abVillarreal finished ahead of Real Sociedad on head-to-head points: Villarreal 5–1 Real Sociedad, Real Sociedad 1–2 Villarreal.