He was the son of Rafał Leszczyński, count of Leszno, and Anna Radzimińska.[2] After the death of his father in 1636 he inherited Leszno, Radzymin and part of Warsawian Praga. Bogusław married twice, first to Countess Anna Dönhoff, from a prominent Pomeranian family, in 1629 and later to the daughter of Court and Grand Marshal Prince Aleksander Ludwik Radziwiłł, princess Joanna Katarzyna Radziwiłł, in 1658.
During the Swedish invasion of 1655 ("The Deluge"), he was committed by a chapter of the Sejm to defend the province of Greater Poland, but instead Bogusław began to negotiate with the Swedes and the Prussian elector.
Although considered a great speaker, he was also criticised by many for being selfish and dishonorable. He was suspected of defalcation of money and royal jewels. A telling story is that when he was offered a Chancellor's post, he bribed the members of the parliament to grant him "absolution", and when one of them later opposed him, he asked, curious: "Who's this son of a bitch that I failed to pay off?" After his death in 1659, deputies of the Sejm in 1662 were appointed to take matters up with his beneficiaries.
Bogusław held the following Sejm positions in Warsaw:
Marshal of the ordinary Sejm on 20 July – 4 October 1641,
^ abRobert I. Frost (2004) After the Deluge: Poland–Lithuania and the Second Northern War, 1655-1660, Cambridge University Press, ISBN0-521-54402-5, p. xvii
^Jan Grzywiński (1938) (in Polish). Kalendarz Ilustrowany kuryer codzienny. Krakow: Nakł. wydawn. "Ilustr. kuryera codziennego". Volume 11, p. 222. OCLC145393368.