ARTIKELDIGITAL.COM

Kappler, U.; Schäfer, H. (2014). "Chapter 11. Transformations of Dimethylsulfide". In Kroneck, P. M. H.; Sosa Torres, M. E. (eds.). The Metal-Driven...

Borane dimethylsulfide (BMS) is a chemical compound with the chemical formula BH3·S(CH3)2. It is an adduct between borane molecule (BH3) and dimethyl...

synthesis of organic compounds. A common alternative to BH3•THF is borane–dimethylsulfide, which has a longer shelf life and effects similar transformations...

on hydroboration relied on diborane, it has been replaced by borane dimethylsulfide, which is more safely handled. Pyrolysis of diborane gives hydrogen...

is produced by the reduction of the amino acid tyrosine with borane dimethylsulfide. The compound, which is chiral, is an example of a 1,2-ethanolamine...

(RCO2H) to esters RCO2CH2SCH3. The compound is prepared by treatment of dimethylsulfide with sulfuryl chloride. "Chloromethyl methyl sulfide". pubchem.ncbi...

into dimethylsulfide and acrylate. M. thiooxydans has been implicated as a dominant organism in phytoplankton blooms, where it consumes dimethylsulfide, methanol...

generate dimethylsulfide, these are often colloquially summarized as DMSO-oxidations. Conceptually, generating an aldehyde and dimethylsulfide from an...

hydroboration employed diborane as a source of BH3. Usually however, borane dimethylsulfide complex BH3S(CH3)2 (BMS) is used instead. It can be obtained in highly...

organic substituents are indicated by the prefixes. (CH3)2S is called dimethylsulfide. Some sulfides are named by modifying the common name for the corresponding...

Dimethyl-sulfide monooxygenase (EC 1.14.13.131, dimethylsulfide monooxygenase) is an enzyme with systematic name dimethyl sulfide,NADH:oxygen oxidoreductase...

this catalyst is used along with borane-tetrahydrofuran (THF), borane-dimethylsulfide, borane-N,N-diethylaniline, or diborane as the borane source. Enantioselective...

volatile substances such as hydrogen disulfide, methional, methionol, dimethylsulfide, and methylmercaptan, which are formed from amino acids that contain...

alkylation of dimethylsulfide with allyl iodide gives trimethylsulfonium iodide. In a related process, secondary alkyl halides react with dimethylsulfide to give...

Jonathan A.; Taylor, Karl E.; Ghan, Steven J. (1991). "Planktonic dimethylsulfide and cloud albedo: An estimate of the feedback response". Climatic Change...

Methylophaga sulfidovorans is an obligately methylotrophic, aerobic, dimethylsulfide-oxidizing bacterium. It is Gram-negative, oval, with strain RB-1. Dezwart...

in the 1940s by Standard Oil of Indiana, was based on oxidation of dimethylsulfide by O 2 from air. Although inexpensive, this process suffered from a...

99° in both free thioethers and their complexes. The C-S distance in dimethylsulfide is 1.81 Å, which is also unaffected in its complexes. The stereochemistry...

fish Isovaleric acid carboxylic acid 0.000078 vomit tert-Butyl mercaptan thiol 0.0000029 Natural gas Dimethylsulfide thioether 0.003 putrified flesh...

sulfide:cytochrome-c2 oxidoreductase. It is also known by the name dimethylsulfide dehydrogenase (Ddh). This enzyme catalyses the following chemical reaction...

stable, but may be easily oxidised in air. Solutions containing borane dimethylsulfide and borane–tetrahydrofuran are commercially available; in tetrahydrofuran...

was achieved via an enantioselective CBS reduction using a borane-dimethylsulfide complex. Corey-Fuchs alkyne synthesis is the synthesis of terminal...

volatile sulfur compounds (i.e., VSC: hydrogen sulfide; methylmercaptan; dimethylsulfide) with each exhalation, creating a 'malodorous cloud' in their vicinity"...

roles in the biogeochemical cycling of methanol, monomethylamine, dimethylsulfide and methyl bromide. All known species are methylotrophic and grow on...

239–247. Dacey, J. W. H.; S. Wakeham (19 September 1986). "Oceanic dimethylsulfide: Production during zooplankton grazing on phytoplankton". Science....

Tert-butylamine borane (tBuNH2→BH3) Phosphine-borane (R3P→BH3) Borane dimethylsulfide ((CH3)2S→BH3) Borane–tetrahydrofuran (THF→BH3) "Method for producing...

form diborane, B2H6. Its adduct borane–tetrahydrofuran and borane–dimethylsulfide are useful in hydroboration reactions. Greenwood, Norman N.; Earnshaw...

PMC 5569953. PMID 28861463. Dacey, J. W. H.; Wakeham, S. G. (1986). "Oceanic Dimethylsulfide: Production During Zooplankton Grazing on Phytoplankton". Science....

hydroboration of α-pinene has been extensively examined. With borane-dimethylsulfide, two equivalents of α-pinene react to give (diisopinocampheyl)borane...

ozonolysis. Often the reaction procedure includes a mild reductant, such as dimethylsulfide (SMe2): RCH=CHR' + O3 + SMe2 → RCHO + R'CHO + O=SMe2 R2C=CHR' + O3...

produced from decaborane and formaldehyde, followed by addition of borane dimethylsulfide. Monocarboranes are precursors to weakly coordinating anions. Dicarbaboranes...

The enzyme DMSO reductase catalyzes the interconversion of DMSO and dimethylsulfide. Naturally occurring chiral sulfoxides include alliin and ajoene. Gama...

of the type species Thiobacillus thioparus can use the sulfur from dimethylsulfide, dimethyldisulfide, or carbon disulfide to support autotrophic growth...

; Kiene, R. P.; Leck, C. (1999). "A global database of sea surface dimethylsulfide (DMS) measurements and a procedure to predict sea surface DMS as a...

J. C.; Schafer, H. (2011). "Purification and Characterization of Dimethylsulfide Monooxygenase from Hyphomicrobium sulfonivorans". Journal of Bacteriology...

trimethylsulfonium + tetrahydrofolate ⇌ {\displaystyle \rightleftharpoons } dimethylsulfide + 5-methyltetrahydrofolate Thus, the two substrates of this enzyme...

emissions and aerosols over the tropical South Atlantic, 3. Atmospheric dimethylsulfide, aerosols and cloud condensation nuclei". J. Geophys. Res. 100 (D6):...

sinks below the photic zone, and less than 1% reaches the seafloor. Dimethylsulfide loss within the photic zone is controlled by microbial uptake and photochemical...

condensation nuclei from the oxidation of the sulfur-containing compound dimethylsulfide, research which has implications for the role of sulfur compounds on...

22 July 2019. Simó, R.; Dachs, J. (2002). "Global ocean emission of dimethylsulfide predicted from biogeophysical data". Global Biogeochemical Cycles....

PMID 9226910. Boden, Rich; Murrell, J. Colin; Schäfer, Hendrik (2011). "Dimethylsulfide is an energy source for the heterotrophic marine bacterium Sagittula...

system Bridge management system Building management system Borane dimethylsulfide, a chemical Bone marrow suppression Burning mouth syndrome, also known...

Fontaine, Frédéric-Georges (2014-08-28). "Lewis base activation of borane–dimethylsulfide into strongly reducing ion pairs for the transformation of carbon dioxide...

Dimethylformamide organic compound; a common solvent for chemical reactions Dimethylsulfide organosulfur compound; used in petroleum refining and in petrochemical...

Catecholborane is less reactive in hydroborations than borane-THF or borane-dimethylsulfide. When catecholborane is treated with a terminal alkyne, a trans vinylborane...

Propargyl bromide is an alkylating agent. For example, it reacts with dimethylsulfide, it reacts to give the sulfonium salt: HCCCH2Br + S(CH3)2 → [HCCCH2S(CH3)2]Br...

methyltransferase from Methanosarcina barkeri, an enzyme of methanogenesis from dimethylsulfide and methylmercaptopropionate". Journal of Bacteriology. 179 (22): 6902–11...

sources, role in the marine food web, and biological degradation to dimethylsulfide". Applied and Environmental Microbiology. 68 (12): 5804–15. Bibcode:2002ApEnM...

aerosols in highly polluted regions. Specifically, phytoplankton emit dimethylsulfide, and its derivate sulfate promotes cloud condensation. Understanding...

Bergeijk, L. J. Stal (January 2001). "Dimethylsulfoniopropionate and dimethylsulfide in the marine flatworm Convoluta roscoffensis and its algal symbiont"...

acetate, CID:70104936 (4). Reduction of the imide with Borane dimethylsulfide afforded [182621-51-8] (5). The reaction of this intermediate with...

in a nucleophilic displacement and the resulting spacer group is a dimethylsulfide (CH2SCH2). In this experiment the guests were the molecules already...

13.244: phenol 2-monooxygenase (NADH) EC 1.14.13.245: assimilatory dimethylsulfide S-monooxygenase EC 1.14.13.246: 4β-methylsterol monooxygenase EC 1...

solution-phase syntheses of tetrahalodiboranes(4) and their labile dimethylsulfide adducts". Chemical Communications (59). doi:10.1039/C7CC03148C. Urry...

[Pd(Me-DuPhos(MeCN)2)](BF4)2 Mono oxidation of (R,R)-Me-Duphos using borane dimethylsulfide as protective group and hydrogen peroxide as oxidizing agent gives...

causes of the Permian–Triassic extinction event.[citation needed] Dimethylsulfide [(CH3)2S or DMS] is produced by the decomposition of dimethylsulfoniopropionate...

Giacomo R. (1996), "Particulate Dimethylsulfoniopropionate Removal and Dimethylsulfide Production by Zooplankton in the Southern Ocean", in Kiene, Ronald...

prepared by reaction of trifluoroethanol with boron trichloride, borane dimethylsulfide, boron tribromide, or boric anhydride. The latter is more convenient...

C4H12SSi trimethylsilyl methyl sulfide 3908-55-2 C4H12SZn dimethylzinc dimethylsulfide complex 91071-61-3 C4H12SeZn dimethylzinc dimethylselenium complex...

traps. Electron donors (e.g. nucleophiles, Lewis bases) for example dimethylsulfide and dimethylsulfoxide are believed to stabilize the carbocation. The...

Hisayoshi; Nakamura, Tomoki (27 February 2023). "PAHs, hydrocarbons, and dimethylsulfides in Asteroid Ryugu samples A0106 and C0107 and the Orgueil (CI1) meteorite"...

cannot only metabolize dimethylsulfoniopropionate (DMSP) to produce dimethylsulfide (DMS), but also use DMSP as a carbon source for growth and survival...

important role in the carbon cycle. DMSP is oxidized by other plankton to dimethylsulfide (DMS), a compound which is linked to cloud formation. Because clouds...

Damm, Ellen; Farías, Laura (May 2013). "Methane production induced by dimethylsulfide in surface water of an upwelling ecosystem" (PDF). Progress in Oceanography...

(DMSP). DMSP can be catabolized either via means of cleavage to dimethylsulfide (DMS) or demethylation by bacterioplankton, in which both have contrasting...

frontier. Kappler U, Schäfer H (2014). "Chapter 11. Transformations of Dimethylsulfide". In Kroneck PM, Torres ME (eds.). The Metal-Driven Biogeochemistry...

methylated amines, methyl halides, and methylated sulfur compounds, such as dimethylsulfide (DMS) and dimethylsulfoxide (DMSO). Some of these compounds are produced...

susceptible to alkylation: PtCl2(SMe2)2 + 2 MeLi → PtMe2(SMe2)2 + 2 LiCl The dimethylsulfide ligands in PtMe2(SMe2)2 can be displaced by other ligands. Many organoplatinum(II)...

emissions and aerosols over the tropical South Atlantic: 3. Atmospheric dimethylsulfide, aerosols and cloud condensation nuclei". Journal of Geophysical Research...

solution-phase syntheses of tetrahalodiboranes(4) and their labile dimethylsulfide adducts". Chemical Communications. 53 (59): 8265–8267. doi:10.1039/c7cc03148c...

Borodonia-Wood pathway based on microbial growth on dimethylsulfone and dimethylsulfide in Hyphomicrobium sulfonivorans. The genera Acidithiobacillus and Thermithiobacillus...