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In organometallic chemistry, the isolobal principle (more formally known as the isolobal analogy) is a strategy used to relate the structure of organic...

is isolobal, hence the rules are applicable to carboranes. This can be explained due to a frontier orbital treatment. Additionally there are isolobal transition-metal...

a benzene ring in which two of the C-H fragments have been replaced by isolobal nitrogen. There are three structural isomers: pyridazine (1,2-diazine)...

was soon understood by many organometallic chemists that a Cp ligand is isolobal to Tp. As many insights into chemistry can be obtained by the study of...

1965 prize for other work.) In his Nobel Lecture, Hoffmann introduced the isolobal analogy for predicting the bonding properties of organometallic compounds...

dimanganese decacarbonyl is formed in terms of the isolobal analogy of two d7 Mn(CO)5 fragments, that are isolobal to the methyl radical CH• 3. In analogy to...

Series of mixed organic and inorganic tetrahedrane structures illustrating that Co(CO)3 and methylidyne are isolobal....

of the hydrogen or substituent on the carbon—the overall replacement is isolobal. 6-membered rings with one nitrogen atom: pyridines 6-membered rings with...

d-electron count, the 18-electron rule, oxidation state, valency, and the isolobal analogy. Many procedures have been reported for the synthesis of Mn2(CO)10...

system with two more electrons, making the cyclopropyl methyl cation's HOMO isolobal to the allyl anion's HOMO. Zvi Rappoport (Ed.), The Chemistry of the Cyclopropyl...

the same number of electrons but they do not have the same structure. Isolobal principle IUPAC, Compendium of Chemical Terminology, 5th ed. (the "Gold...

organometallic compounds is often discussed from the perspective of the isolobal principle. A wide variety of physical techniques are used to determine...

with other more or less related ligand systems that may or may not be isolobal and/or isoelectronic with the ansa-bridged cyclopentadienyl amido ligand...

electron deficient, monomeric thallium iron carbonylate isostructural and isolobal to diiron nonacarbonyl". Journal of Organometallic Chemistry. 614–615:...

identified by single crystal X-ray crystallography. Stable carbenes are roughly isolobal with organophosphines. The carbenic lone pair is a good σ donor, and the...

intermediate, pentaarsaferrocene ([CpRFe(μ5-As5)]). This intermediate, isolobal to ferrocene, replaces one of the cyclopentadienyl ligands with a cyclic...

Lewis-acidic antimony compounds have been investigated to extend the isolobal analogy between the vacant p orbital of borane and σ*(Sb–X) orbitals of...

unit in the parent o-carborane are missing. The compound resembles and is isolobal with benzyne. A carboryne compound was first generated in 1990 starting...

were first mentioned by the group of Vol’pin in Moscow in 1961. Using the isolobal analogy, the group argued that silacyclopropanes would be a stable group...

G.; Sadighi, Joseph P. (2012). "Synthesis of a Trigold Monocation: An Isolobal Analogue of [H3]+". Angewandte Chemie International Edition. 51 (48): 12077–12080...

close in energy, leading to interesting interactions overall. From the isolobal principle, we can expect the bonding properties to be similar in borirenes:...

to another metal. For example, cyclopentadienyldicarbonyliron (Fp) is isolobally a pseudohalide: With cobalt tetracarbonyl instead of Fp, there exist similar...

"N-Heterocyclic Phosphenium Ligands as Sterically and Electronically-Tunable Isolobal Analogues of Nitrosyls". Inorganic Chemistry. 51 (7): 4170–4179. doi:10...

synthesized by first have m-terphenyls as the ligands on the metal, and then an isolobal exchange occurs, placing the boryl ligands onto the metal and allowing...

carbene analogs as well, most notably phosphenium ions (R2P+) which are isolobal with (hetero-)carbenes possessing a singlet ground state. Carbene analogs...

homoleptic trimetallic non-carbonyl cluster featuring hydrocarbon ligands. An isolobal analogy can be made with the related Fe3(CO)10 (μ-CO)2 cluster first prepared...