Arsenide iodide

Arsenide iodides or iodide arsenides are compounds containing anions composed of iodide (I⁻) and arsenide (As³⁻). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the arsenide chlorides, arsenide bromides, phosphide iodides, and antimonide iodides.

List

formula	system	space group	unit cell Å	volume	density	comment	ref
Ca₂AsI	trigonal	R3m	a=4.397, c = 22.29, Z = 3		3.76	brown	^[1]^[2]
Ca₃AsI₃	cubic	I4₁32	a=12.42		3.99	colourless	^[1]
Cu₂P_1.8As_1.2I₂	monoclinic	P2₁/c	a = 15.477, b = 13.200, c = 15.421, β = 115.406°, Z = 16			Cu exchangeable with Ag; band gap 1.2 eV	^[3]
Ge₃₈As₈I₈	cubic	P43m	a=10.611			metallic; water and air stable	^[4]
Ag₂P_1.8As_1.2I₂	monoclinic	P2₁/c	a = 15.84, b = 13.68, c = 15.58 and β = 117.63° Z=16				^[5]
Sn₂₄As_19.3I₈	cubic		a=22.179 Z=8			black	^[6]
Sn_20.5□_3.5As₂₂I₈	cubic		a=22.1837			low thermal conductivity	^[7]
Sn₂₄As_xP_19.3−xI_{8 x=0-16}	cubic	Pm3n	a = 10.9358—11.1495				^[8]
Sn_19.3Cu_4.7As₂₂I₈	cubic	Pm3n	a = 11.1736 Z = 1	1394.4	6.236	clathrate; Zintl; diamagnetic	^[9]
Sn_24–x–δIn_xAs_22–yI₈	cubic	Pm3n	a = 11.088 (x = 0) to a = 11.343 (x = 10.7)			clathrate	^[10]
La₂AsI₂	trigonal	P3m1	a=4.3795 c=10.910		5.56		^[11]
Hg₄AsI₅	orthorhombic	Cmca	a=11.927 b=12.128 c=19.776 Z=8	2859.0	7.025	red	^[12]
Hg₄As₂I₃	cubic	Pa3	a=12.999 Z=8	2196	8.06	black	^[13]
HgI₂⋅As₄S₄	monoclinic	P2₁/c	a=9.433 b=14.986 c=11.624 β=127.72° Z=4	1299	4.509	orange; dec 212 °C	^[14]
Hg₅AsS₂I₃	monoclinic	C2/c	a=13.339 b=8.444 c=13.428 β=118.352 Z=4	1331.2	7.599	black; dec 150 °C	^[15]
Hg₃AsSe₄I	hexagonal	P6₃mc	a = 7.6902, c = 9.968 Z=2			red; air stable	^[16]
[Hg₇As₄](AgI₃)₂	cubic	Pa	a = 13.138 Z = 4				^[17]^[18]
(Hg₂As)₂(CdI₄)	monoclinic	P2₁	a=7.945, b=12.934, c=8.094, β=116.898°	741.7			^[19]
[Hg₇As₄I₃](SnI₃)	cubic	P2₁3	a = 13.110, Z = 4	2253.2	7.617	black	^[20]

References

^ ^a ^b Hadenfeldt, C.; Fester, W. (July 1982). "Reindarstellung und thermische Stabilität von Calcium-phosphid- und -arsenidiodiden: Ca3PI3, Ca3AsI3, Ca2PI und Ca2AsI". Zeitschrift für anorganische und allgemeine Chemie (in German). 490 (1): 25–30. doi:10.1002/zaac.19824900105. ISSN 0044-2313.
^ Hadenfeldt, C.; Herdejürgen, H. (February 1987). "Darstellung und Kristallstruktur der Calciumnitridhalogenide Ca2NCl und Ca2NBr". Zeitschrift für anorganische und allgemeine Chemie (in German). 545 (2): 177–183. doi:10.1002/zaac.19875450220. ISSN 0044-2313.
^ Jayasekera, Buddhimathie; Aitken, Jennifer A.; Heeg, Mary Jane; Brock, Stephanie L. (2003-02-01). "Toward an Arsenic Analogue of Hittorf's Phosphorus: Mixed Pnicogen Chains in Cu 2 P 1.8 As 1.2 I 2". Inorganic Chemistry. 42 (3): 658–660. doi:10.1021/ic0258936. ISSN 0020-1669. PMID 12562174.
^ von Schnering, Hans-Georg; Menke, Heinz (January 1972). "Ge38P8I8 and Ge38As8I8, a New Class of Compounds with Clathrate Structure". Angewandte Chemie International Edition in English. 11 (1): 43–44. doi:10.1002/anie.197200431. ISSN 0570-0833.
^ Jayasekera, Buddhimathie; Brock, Stephanie L. (2002). "Ag Ion-Exchange Reactions of Cu 2 P 3 I 2 and Cu 2 P 1.8 As 1.2 I 2". MRS Proceedings. 755: DD6.12. doi:10.1557/PROC-755-DD6.12. ISSN 0272-9172.
^ Shatruk, Mikhail M.; Kovnir, Kirill A.; Shevelkov, Andrei V.; Presniakov, Igor A.; Popovkin, Boris A. (1999-07-01). "First Tin Pnictide Halides Sn 24 P 19.3 I 8 and Sn 24 As 19.3 I 8 : Synthesis and the Clathrate-I Type of the Crystal Structure". Inorganic Chemistry. 38 (15): 3455–3457. doi:10.1021/ic990153r. ISSN 0020-1669. PMID 11671088.
^ Zaikina, Julia V.; Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Prots, Yuri; Baitinger, Michael; Schnelle, Walter; Olenev, Andrei V.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Grin, Yuri (2007-06-15). "Sn20.5□3.5As22I8: A Largely Disordered Cationic Clathrate with a New Type of Superstructure and Abnormally Low Thermal Conductivity". Chemistry - A European Journal. 13 (18): 5090–5099. doi:10.1002/chem.200601772. PMID 17385200.
^ Kelm, E. A.; Zaikina, Yu. V.; Dikarev, E. V.; Shevelkov, A. V. (April 2009). "Distribution of phosphorus and arsenic atoms in the solid solution Sn24As x P19.3-x I8 with the structure of clathrate-I". Russian Chemical Bulletin. 58 (4): 746–750. doi:10.1007/s11172-009-0089-0. ISSN 1066-5285. S2CID 93897495.
^ Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Schnelle, Walter; Grin, Yuri; Shevelkov, Andrei V. (2005-11-01). "Sn 19.3 Cu 4.7 As 22 I 8 : a New Clathrate-I Compound with Transition-Metal Atoms in the Cationic Framework" (PDF). Inorganic Chemistry. 44 (24): 8786–8793. doi:10.1021/ic051160k. ISSN 0020-1669. PMID 16296833.
^ Kelm, Evgeny A.; Olenev, Andrei V.; Bykov, Mikhail A.; Sobolev, Alexey V.; Presniakov, Igor A.; Kulbachinskii, Vladimir A.; Kytin, Vladimir G.; Shevelkov, Andrei V. (November 2011). "Synthesis, Crystal Structure, and Thermoelectric Properties of Clathrates in the Sn-In-As-I System". Zeitschrift für anorganische und allgemeine Chemie. 637 (13): 2059–2067. doi:10.1002/zaac.201100287.
^ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.
^ Oleneva, O. S.; Shestimerova, T. A.; Olenev, A. V.; Dikarev, E. V.; Shevelkov, A. V. (May 2006). "Synthesis and the crystal and electronic structure of Hg4AsI5". Russian Chemical Bulletin. 55 (5): 762–765. doi:10.1007/s11172-006-0329-5. ISSN 1066-5285. S2CID 97240594.
^ Labbé, Ph.; Ledésert, M.; Raveau, B.; Rebbah, A. (1989-08-01). "Crystal structure of Hg 4 As 2 I 3". Zeitschrift für Kristallographie - Crystalline Materials. 187 (1–4): 117–124. doi:10.1524/zkri.1989.187.14.117. ISSN 2196-7105. S2CID 101349696.
^ Bräu, Michael F.; Pfitzner, Arno (2006-07-03). "HgI2⋅As4S4: An Adduct from HgI2 Molecules and Undistorted As4S4 Cages". Angewandte Chemie International Edition. 45 (27): 4464–4467. doi:10.1002/anie.200600690. ISSN 1433-7851. PMID 16758498.
^ Liu, Yong; Zeng, Hui-Yi; Liu, Bin-Wen; Wang, Geng-E; Guo, Guo-Cong (May 2015). "Hg 5 AsS 2 I 3 – A Narrow-Band-Gap 2D Layered Compound with Different Trapped I – Anions". European Journal of Inorganic Chemistry. 2015 (14): 2402–2406. doi:10.1002/ejic.201500150. ISSN 1434-1948.
^ Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01). "Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure". Inorganic Chemistry. 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388.
^ Olenev, Andrei V.; Baranov, Alexei I.; Oleneva, Olga S.; Vorontsov, Ivan I.; Antipin, Mikhail Yu.; Shevelkov, Andrei V. (March 2003). "Synthesis, Crystal and Electronic Structure of [Hg 7 As 4 ](AgI 3 ) 2 , a Novel Supramolecular Complex with the Off-Plane AgI 3 2− Guest Anion". European Journal of Inorganic Chemistry. 2003 (6): 1053–1057. doi:10.1002/ejic.200390137. ISSN 1434-1948.
^ Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020). "Crystallographic Analysis and Symmetry Generation for Some Structures with [As2] and [Hgn] (n = 2, 3) Cluster Groups". Journal of Structural Chemistry. 61 (2): 259–266. doi:10.1134/S0022476620020109. ISSN 0022-4766. S2CID 220540955.
^ Zou, Jian-Ping; Wu, Dong-Sheng; Huang, Shu-Ping; Zhu, Jing; Guo, Guo-Cong; Huang, Jin-Shun (March 2007). "Synthesis, crystal and band structures, and properties of a new supramolecular complex (Hg2As)2(CdI4)". Journal of Solid State Chemistry. 180 (3): 805–811. Bibcode:2007JSSCh.180..805Z. doi:10.1016/j.jssc.2006.11.018.
^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2000). "[Hg7As4I3](SnI3): Trapping the SnI31– Anion in the Cavities of the Unprecedented Mercury-Arsenic-Iodine Network". European Journal of Inorganic Chemistry. 2000 (2): 265–270. doi:10.1002/(SICI)1099-0682(200002)2000:2<265::AID-EJIC265>3.0.CO;2-A.

[:0-1] Hadenfeldt, C.; Fester, W. (July 1982). "Reindarstellung und thermische Stabilität von Calcium-phosphid- und -arsenidiodiden: Ca3PI3, Ca3AsI3, Ca2PI und Ca2AsI". Zeitschrift für anorganische und allgemeine Chemie (in German). 490 (1): 25–30. doi:10.1002/zaac.19824900105. ISSN 0044-2313.

[2] Hadenfeldt, C.; Herdejürgen, H. (February 1987). "Darstellung und Kristallstruktur der Calciumnitridhalogenide Ca2NCl und Ca2NBr". Zeitschrift für anorganische und allgemeine Chemie (in German). 545 (2): 177–183. doi:10.1002/zaac.19875450220. ISSN 0044-2313.

[3] Jayasekera, Buddhimathie; Aitken, Jennifer A.; Heeg, Mary Jane; Brock, Stephanie L. (2003-02-01). "Toward an Arsenic Analogue of Hittorf's Phosphorus: Mixed Pnicogen Chains in Cu 2 P 1.8 As 1.2 I 2". Inorganic Chemistry. 42 (3): 658–660. doi:10.1021/ic0258936. ISSN 0020-1669. PMID 12562174.

[4] von Schnering, Hans-Georg; Menke, Heinz (January 1972). "Ge38P8I8 and Ge38As8I8, a New Class of Compounds with Clathrate Structure". Angewandte Chemie International Edition in English. 11 (1): 43–44. doi:10.1002/anie.197200431. ISSN 0570-0833.

[5] Jayasekera, Buddhimathie; Brock, Stephanie L. (2002). "Ag Ion-Exchange Reactions of Cu 2 P 3 I 2 and Cu 2 P 1.8 As 1.2 I 2". MRS Proceedings. 755: DD6.12. doi:10.1557/PROC-755-DD6.12. ISSN 0272-9172.

[6] Shatruk, Mikhail M.; Kovnir, Kirill A.; Shevelkov, Andrei V.; Presniakov, Igor A.; Popovkin, Boris A. (1999-07-01). "First Tin Pnictide Halides Sn 24 P 19.3 I 8 and Sn 24 As 19.3 I 8 : Synthesis and the Clathrate-I Type of the Crystal Structure". Inorganic Chemistry. 38 (15): 3455–3457. doi:10.1021/ic990153r. ISSN 0020-1669. PMID 11671088.

[7] Zaikina, Julia V.; Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Prots, Yuri; Baitinger, Michael; Schnelle, Walter; Olenev, Andrei V.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Grin, Yuri (2007-06-15). "Sn20.5□3.5As22I8: A Largely Disordered Cationic Clathrate with a New Type of Superstructure and Abnormally Low Thermal Conductivity". Chemistry - A European Journal. 13 (18): 5090–5099. doi:10.1002/chem.200601772. PMID 17385200.

[8] Kelm, E. A.; Zaikina, Yu. V.; Dikarev, E. V.; Shevelkov, A. V. (April 2009). "Distribution of phosphorus and arsenic atoms in the solid solution Sn24As x P19.3-x I8 with the structure of clathrate-I". Russian Chemical Bulletin. 58 (4): 746–750. doi:10.1007/s11172-009-0089-0. ISSN 1066-5285. S2CID 93897495.

[9] Kovnir, Kirill A.; Sobolev, Alexei V.; Presniakov, Igor A.; Lebedev, Oleg I.; Van Tendeloo, Gustaaf; Schnelle, Walter; Grin, Yuri; Shevelkov, Andrei V. (2005-11-01). "Sn 19.3 Cu 4.7 As 22 I 8 : a New Clathrate-I Compound with Transition-Metal Atoms in the Cationic Framework" (PDF). Inorganic Chemistry. 44 (24): 8786–8793. doi:10.1021/ic051160k. ISSN 0020-1669. PMID 16296833.

[10] Kelm, Evgeny A.; Olenev, Andrei V.; Bykov, Mikhail A.; Sobolev, Alexey V.; Presniakov, Igor A.; Kulbachinskii, Vladimir A.; Kytin, Vladimir G.; Shevelkov, Andrei V. (November 2011). "Synthesis, Crystal Structure, and Thermoelectric Properties of Clathrates in the Sn-In-As-I System". Zeitschrift für anorganische und allgemeine Chemie. 637 (13): 2059–2067. doi:10.1002/zaac.201100287.

[11] Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.

[12] Oleneva, O. S.; Shestimerova, T. A.; Olenev, A. V.; Dikarev, E. V.; Shevelkov, A. V. (May 2006). "Synthesis and the crystal and electronic structure of Hg4AsI5". Russian Chemical Bulletin. 55 (5): 762–765. doi:10.1007/s11172-006-0329-5. ISSN 1066-5285. S2CID 97240594.

[13] Labbé, Ph.; Ledésert, M.; Raveau, B.; Rebbah, A. (1989-08-01). "Crystal structure of Hg 4 As 2 I 3". Zeitschrift für Kristallographie - Crystalline Materials. 187 (1–4): 117–124. doi:10.1524/zkri.1989.187.14.117. ISSN 2196-7105. S2CID 101349696.

[14] Bräu, Michael F.; Pfitzner, Arno (2006-07-03). "HgI2⋅As4S4: An Adduct from HgI2 Molecules and Undistorted As4S4 Cages". Angewandte Chemie International Edition. 45 (27): 4464–4467. doi:10.1002/anie.200600690. ISSN 1433-7851. PMID 16758498.

[15] Liu, Yong; Zeng, Hui-Yi; Liu, Bin-Wen; Wang, Geng-E; Guo, Guo-Cong (May 2015). "Hg 5 AsS 2 I 3 – A Narrow-Band-Gap 2D Layered Compound with Different Trapped I – Anions". European Journal of Inorganic Chemistry. 2015 (14): 2402–2406. doi:10.1002/ejic.201500150. ISSN 1434-1948.

[16] Beck, Johannes; Hedderich, Sylvia; Köllisch, Klaus (2000-12-01). "Hg 3 AsE 4 X (E = S, Se; X = Cl, Br, I), a Family of Isotypic Compounds with an Acentric, Layered Structure". Inorganic Chemistry. 39 (25): 5847–5850. doi:10.1021/ic0003527. ISSN 0020-1669. PMID 11151388.

[17] Olenev, Andrei V.; Baranov, Alexei I.; Oleneva, Olga S.; Vorontsov, Ivan I.; Antipin, Mikhail Yu.; Shevelkov, Andrei V. (March 2003). "Synthesis, Crystal and Electronic Structure of [Hg 7 As 4 ](AgI 3 ) 2 , a Novel Supramolecular Complex with the Off-Plane AgI 3 2− Guest Anion". European Journal of Inorganic Chemistry. 2003 (6): 1053–1057. doi:10.1002/ejic.200390137. ISSN 1434-1948.

[18] Borisov, S. V.; Pervukhina, N. V.; Magarill, S. A. (February 2020). "Crystallographic Analysis and Symmetry Generation for Some Structures with [As2] and [Hgn] (n = 2, 3) Cluster Groups". Journal of Structural Chemistry. 61 (2): 259–266. doi:10.1134/S0022476620020109. ISSN 0022-4766. S2CID 220540955.

[19] Zou, Jian-Ping; Wu, Dong-Sheng; Huang, Shu-Ping; Zhu, Jing; Guo, Guo-Cong; Huang, Jin-Shun (March 2007). "Synthesis, crystal and band structures, and properties of a new supramolecular complex (Hg2As)2(CdI4)". Journal of Solid State Chemistry. 180 (3): 805–811. Bibcode:2007JSSCh.180..805Z. doi:10.1016/j.jssc.2006.11.018.

[20] Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2000). "[Hg7As4I3](SnI3): Trapping the SnI31– Anion in the Cavities of the Unprecedented Mercury-Arsenic-Iodine Network". European Journal of Inorganic Chemistry. 2000 (2): 265–270. doi:10.1002/(SICI)1099-0682(200002)2000:2<265::AID-EJIC265>3.0.CO;2-A.

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Arsenide iodide

List

References

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