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Calcium chlorate

Calcium chlorate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.331 Edit this at Wikidata
EC Number
  • 233-378-2
RTECS number
  • FN9800000
UNII
  • InChI=1S/Ca.2ClHO3/c;2*2-1(3)4/h;2*(H,2,3,4)/q+2;;/p-2 checkY
    Key: YALMXYPQBUJUME-UHFFFAOYSA-L checkY
  • InChI=1/Ca.2ClHO3/c;2*2-1(3)4/h;2*(H,2,3,4)/q+2;;/p-2
    Key: YALMXYPQBUJUME-NUQVWONBAM
  • [Ca+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O
Properties
Ca(ClO3)2
Molar mass 206.98 g/mol
Appearance white solid
deliquescent
Odor odorless
Density 2.71 g/cm3
Melting point 150°C (dihydrate, decomp)
325°C
209 g/100mL (20 °C)
197 g/100mL (25 °C)
Structure
monoclinic
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazard OX: Oxidizer. E.g. potassium perchlorate
1
0
1
OX
Related compounds
Other anions
 calcium chloride
calcium bromate
calcium bromide
Other cations
 potassium chlorate
sodium chlorate
barium chlorate
magnesium chlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Calcium chlorate is the calcium salt of chloric acid, with the chemical formula Ca(ClO3)2. Like other chlorates, it is a strong oxidizer.

Production

Calcium chlorate is produced by passing chlorine gas through a hot suspension of calcium hydroxide in water, producing calcium hypochlorite, which disproportionates when heated with excess chlorine to give calcium chlorate and calcium chloride:[1]

6 Ca(OH)2 + 6 Cl2 → Ca(ClO3)2 + 5 CaCl2 + 6 H2O

This is also the first step of the Liebig process for the manufacture of potassium chlorate.[citation needed]

In theory, electrolysis of hot calcium chloride solution will produce the chlorate salt,[citation needed] analogous to the process used for the manufacture of sodium chlorate. In practice, electrolysis is complicated by calcium hydroxide depositing on the cathode, preventing the flow of current.

Reactions

When concentrated solutions of calcium chlorate and potassium chloride are combined, potassium chlorate precipitates:[1][2]

Ca(ClO3)2 + 2 KCl → 2 KClO3 + CaCl2

This is the second step of the Liebig process for the manufacture of potassium chlorate.[2]

Solutions of calcium chlorate react with solutions of alkali carbonates to give a precipitate of calcium carbonate and the alkali chlorate in solution:

Ca(ClO3)2 + Na2CO3 → 2 NaClO3 + CaCO3

On strong heating, calcium chlorate decomposes to give oxygen and calcium chloride:

Ca(ClO3)2 → CaCl2 + 3 O2

Cold, dilute solutions of calcium chlorate and sulfuric acid react to give a precipitate of calcium sulfate and chloric acid in solution:[3]

Ca(ClO3)2 + H2SO4 → 2 HClO3 + CaSO4

Contact with strong sulfuric acid can result in explosions[4] due to the instability of concentrated chloric acid. Contact with ammonium compounds can also cause violent decomposition due to the formation of unstable ammonium chlorate.[4]

Uses

Calcium chlorate has been used as an herbicide,[citation needed] like sodium chlorate.

Calcium chlorate is occasionally used in pyrotechnics,[citation needed] as an oxidizer and pink flame colorant. Its hygroscopic nature and incompatibility with other common pyrotechnic materials (such as sulfur) limit its utility in these applications.

References

  1. ^ a b Samuel P. Sadtler, Virgil Coblentz and Jeannot Hostmann (1918). A textbook of chemistry, intended for the use of pharmaceutical and medical students. p. 329.
  2. ^ a b Mellor, Joseph William (1917). Modern Inorganic Chemistry. p. 287.
  3. ^ Ira Remsen, Charles August Rouillu (1883). "American Chemical Journal". 4: 309. Solution of pure calcium chlorate, treated by sulphuric acid, would of course give a solution of chloric acid {{cite journal}}: Cite journal requires |journal= (help)
  4. ^ a b PubChem - Calcium Chlorate: Experimental Properties
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