Chemical compound
Copper(I) acetate
Identifiers
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ChemSpider
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ECHA InfoCard
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100.009.036
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EC Number
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UNII
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InChI=1S/C2H4O2.Cu/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1 Key: RFKZUAOAYVHBOY-UHFFFAOYSA-M
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Properties
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C2H3CuO2
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Molar mass
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122.590 g·mol−1
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Hazards
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GHS labelling:[1]
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Warning
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H315, H319, H335
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P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P501
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Copper(I) acetate (cuprous acetate) is an organic copper salt of acetic acid with chemical formula CH3COOCu.
Under standard conditions, copper(I) acetate is a colorless, odorless crystal.
Chemical propieties
When interacting with water (hydrolysis), copper(I) hydroxide (CuOH) is formed:
- CuCH3COO + H2O → CuOH + CH3COOH
In air, it oxidizes to copper(II) acetate. It forms adducts with organic substances.
Synthesis
- Reaction of copper(II) acetate with hydrogen or copper (reduction process):
- 2 (CH3COO)2Cu + H2 → 2 CH3COOCu + 2 CH3COOH
- (CH3COO)2Cu + Cu → 2 CH3COOCu
Application
Copper(I) acetate is used as a catalyst for the oxidation of phenols.
References