Kampfite

Kampfite
Kampfite
	Traskite (brown) and Kampfite (bluish), from Big Creek, Fresno County, California, United States of America
General
Category	Phyllosilicate
Formula; (repeating unit)	Ba12(Si11Al5)O31(CO3)8Cl5
IMA symbol	Kpfb
Strunz classification	9.EG.20
Crystal system	Monoclinic
Crystal class	Domatic (m) ; (same H-M symbol)
Space group	Cc
Unit cell	a = 31.2329, b = 5.2398 ; c = 9.0966 [Å]; β = 106.933°; Z = 1
Identification
Color	Light blue gray
Crystal habit	Irregular grains or anhedral crystal inclusions
Cleavage	Good on {001}
Fracture	Uneven
Tenacity	Brittle
Mohs scale hardness	3
Luster	Vitreous
Streak	White
Diaphaneity	Translucent
Specific gravity	3.45
Optical properties	Uniaxial – (strongly pseudohexagonal)
Refractive index	nω = 1.642 nε = 1.594
Birefringence	δ = 0.048
References

Kampfite is a rare barium silicate–carbonate–halide mineral with the chemical formula Ba₁₂(Si₁₁Al₅)O₃₁(CO₃)₈Cl₅. Discovered in 1964 and described in 2001, it is named after Anthony R. Kampf. The mineral is known only from Fresno County, California.

Description

Kampfite is translucent and light blue-gray in color. Specimens occur as irregular masses up to 1 cm (0.39 in) in size.^[4]

Composition and structure

When first described, the formula was identified as Ba₆[(Si,Al)O₂]₈(CO₃)₂Cl₂(Cl,H₂O)₂.^[5] Subsequent work on analyzing the crystal structure led to a revised formula of Ba₁₂(Si₁₁Al₅)O₃₁(CO₃)₈Cl₅. The structural H₂O noted in the original description was not found in the later work.^[6]

The structure consists of double layers of tetrahedra connected by barium-containing polyhedra. It is this layering which causes kampfite's one perfect cleavage.^[7]^[8] Kampfite shares chemical and structural similarities with cymrite.^[7] As of 2007^[update], it is the only known barium silicate carbonate aside from fencooperite.^[6]

Occurrence

Kampfite has been found in association with celsian, fresnoite, macdonaldite, pyrrhotite, titantaramellite, traskite, and witherite.^[4] The mineral is known only from locations in Fresno County, California.^[2]^[4] Kampfite is found in quartz-rich regions of sanbornite rocks^[5] within gneiss which has undergone contact metamorphism associated with an adjacent granodiorite intrusive.^[4]

History

The mineral discovered in 1964 by Robert Walstrom from the Esquire #1 claim of the Rush Creek deposit in eastern Fresno County.^[9] It was described in 2001 in The Canadian Mineralogist.^[5] The mineral was named kampfite in honor of Anthony Robert Kampf (1948–), curator of the Los Angeles County Museum of Natural History, for his crystallography work on new and rare minerals.^[9]

Co-type specimens are held by the University of British Columbia and the Geological Survey of Canada.^[10]

References

^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
^ ^a ^b Kampfite on Mindat.org
^ Kampfite data on Webmin
^ ^a ^b ^c ^d Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (eds.). "Kampfite" (PDF). Handbook of Mineralogy. Chantilly, VA: Mineralogical Society of America.
^ ^a ^b ^c Basciano et al. 2001, p. 1053.
^ ^a ^b Basciano & Groat 2007, p. 942.
^ ^a ^b Basciano & Groat 2007, p. 935.
^ Basciano & Groat 2007, p. 940.
^ ^a ^b Basciano et al. 2001, p. 1054.
^ Basciano et al. 2001, pp. 1054–1055.

Bibliography

Basciano, Laurel C.; Groat, Lee A.; Roberts, Andrew C.; Grice, Joel D.; et al. (2001). "Kampfite, a new barium silicate carbonate mineral species from Fresno County, California" (PDF). The Canadian Mineralogist. 39 (4): 1053–1058. Bibcode:2001CaMin..39.1053B. CiteSeerX 10.1.1.553.8742. doi:10.2113/gscanmin.39.4.1053.
Basciano, Laurel C.; Groat, Lee A. (2007). "The crystal structure of kampfite" (PDF). The Canadian Mineralogist. 45 (4): 935–943. Bibcode:2007CaMin..45..935B. doi:10.2113/gscanmin.45.4.935.

External links

Photos of kampfite from mindat.org

[1] Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.

[mindat-2] Kampfite on Mindat.org

[Webmin-3] Kampfite data on Webmin

[handbook-4] Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (eds.). "Kampfite" (PDF). Handbook of Mineralogy. Chantilly, VA: Mineralogical Society of America.

[FOOTNOTEBascianoGroatRobertsGrice20011053-5] Basciano et al. 2001, p. 1053.

[FOOTNOTEBascianoGroat2007942-6] Basciano & Groat 2007, p. 942.

[FOOTNOTEBascianoGroat2007935-7] Basciano & Groat 2007, p. 935.

[FOOTNOTEBascianoGroat2007940-8] Basciano & Groat 2007, p. 940.

[FOOTNOTEBascianoGroatRobertsGrice20011054-9] Basciano et al. 2001, p. 1054.

[FOOTNOTEBascianoGroatRobertsGrice20011054–1055-10] Basciano et al. 2001, pp. 1054–1055.

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