Ruthenium(III) acetate

Ruthenium(III) acetate
Identifiers
CAS Number	55466-76-7 [ECHA];
3D model (JSmol)	Interactive image;
EC Number	259-653-7;
PubChem CID	91886549;
	InChI InChI=1S/6C2H4O2.3H2O.O.3Ru/c61-2(3)4;;;;;;;/h61H3,(H,3,4);31H2;;;;/q;;;;;;;;;;3+2/p-6 Key: KVUJOTGIJBOLLI-UHFFFAOYSA-H ;
	SMILES O1C(C)=[O+][Ru-3]6(O23)([OH2+])([O+]=C(C)O4)[O+]=C(C)O[Ru-3]24([OH2+])([O+]=C(C)O5)[O+]=C(C)O[Ru-3]135([OH2+])[O+]=C(C)O6;
Properties
Chemical formula	C12H28BF4O18Ru3
Molar mass	850.35 g·mol−1
Appearance	green solid
Density	2.110 g/cm3
Structure
Coordination geometry	octahedral
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H318, H410
Precautionary statements	P273, P280, P305+P351+P338, P310, P391, P501
Related compounds
Related compounds	Manganese(III) acetate; Iron(III) acetate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Ruthenium(III) acetate, commonly known as basic ruthenium acetate,^[1] describes a family of salts where the cation has the formula [Ru₃O(O₂CCH₃)₆(OH₂)₃]⁺. A representative derivative is the dihydrate of the tetrafluoroborate salt [Ru₃O(O₂CCH₃)₆(OH₂)₃]BF₄(H₂O)₂, which is the source of the data in the table above.^[2] This and related salts are forest green, air-stable solids that are soluble in alcohols.

Basic ruthenium acetate features octahedral Ru(III) centers, a triply bridging oxo ligand, six acetate ligands, and three aquo ligands. The same structure is shared with basic acetates of iron, chromium, iridium, and manganese.^[1]^[2]

Preparation and reactions

It is prepared by heating ruthenium trichloride in acetic acid in the presence of sodium acetate.^[3] The basic acetates of ruthenium were reported in the early 1950s but were not properly formulated.^[4]

Basic ruthenium acetate reacts with many ligands such as triphenylphosphine and pyridine concomitant with reduction. These derivatives [Ru₃O(O₂CCH₃)₆L₃]⁰ are mixed valence compounds.^[5]

Related compounds

[Ru₂(OAc)₄Cl]_n is a coordination polymer with a composition similar to that of ruthenium(III) acetate.

Diruthenium tetraacetate chloride

References

^ ^a ^b Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
^ ^a ^b O. Almog; A. Bino; D. Garfinkel-Shweky (1993). "The Structure of Oxo-Bridged Trinuclear Ruthenium and Iridium Hexacarboxylates". Inorg. Chim. Acta. 213 (1–2): 99. doi:10.1016/S0020-1693(00)83819-0.
^ J. C. Goeltz; S. D. Glover; J. Hauk; C. P. Kubiak (2010). "Ruthenium Complexes". Inorganic Syntheses. Vol. 35. pp. 156–160. doi:10.1002/9780470651568.ch8. ISBN 978-0-470-65156-8. {{cite book}}: |journal= ignored (help)
^ Martin, F. S. (1952). "Basic Trinuclear Ruthenium Acetate". Journal of the Chemical Society: 2682–4. doi:10.1039/jr9520002682.
^ Cotton, F. A.; Norman, J. G. Jr. (1972). "Structural Characterization of a Basic trinuclear Ruthenium Acetate". Inorg. Chim. Acta. 6: 411–419. doi:10.1016/S0020-1693(00)91829-2.

[G&W-1] Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.

[ICA-2] O. Almog; A. Bino; D. Garfinkel-Shweky (1993). "The Structure of Oxo-Bridged Trinuclear Ruthenium and Iridium Hexacarboxylates". Inorg. Chim. Acta. 213 (1–2): 99. doi:10.1016/S0020-1693(00)83819-0.

[3] J. C. Goeltz; S. D. Glover; J. Hauk; C. P. Kubiak (2010). "Ruthenium Complexes". Inorganic Syntheses. Vol. 35. pp. 156–160. doi:10.1002/9780470651568.ch8. ISBN 978-0-470-65156-8. {{cite book}}: |journal= ignored (help)

[4] Martin, F. S. (1952). "Basic Trinuclear Ruthenium Acetate". Journal of the Chemical Society: 2682–4. doi:10.1039/jr9520002682.

[5] Cotton, F. A.; Norman, J. G. Jr. (1972). "Structural Characterization of a Basic trinuclear Ruthenium Acetate". Inorg. Chim. Acta. 6: 411–419. doi:10.1016/S0020-1693(00)91829-2.

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